Theory of volume transition in polyelectrolyte gels with charge regularization
نویسندگان
چکیده
منابع مشابه
Calcium Induced Volume Transition in Polyelectrolyte Gels
The osmotic properties and the small angle neutron scattering (SANS) behaviour of fully neutralized sodium polyacrylate gels are investigated in the presence of calcium ions. Analysis of the SANS response displays three characteristic length scales, two of which are of thermodynamic origin, while the third, associated with the frozen-in structural inhomogeneities, is static. The SANS results ar...
متن کاملSalt-Induced Swelling and Volume Phase Transition of Polyelectrolyte Gels
A theoretical model of polyelectrolyte gels is presented to study continuous and discontinuous volume phase transitions induced by changing salt concentration in the external solution. Phase diagrams are constructed in terms of the polymer–solvent interaction parameters, external salt concentration, and concentration of fixed charges. Comparisons with previous experiments for an ionized acrylam...
متن کاملMicrophase Separation Transition for Polyelectrolyte Gels in Poor Solvents
The microphase separation transition in the weakly charged polyelectrolyte gels
متن کاملA model of ideal elastomeric gels for polyelectrolyte gels.
The concept of the ideal elastomeric gel is extended to polyelectrolyte gels and verified using a polyacrylamide-co-acrylic acid hydrogel as a model material system. A comparison between mixing and ion osmosis shows that the mixing osmosis is larger than the ion osmosis for small swelling ratios, while the ion osmosis dominates for large swelling ratios. We show further that the non-Gaussian ch...
متن کاملDynamics of interface of gels undergoing volume phase transition
The dynamics of interface of chemical gels undergoing volume phase transition is studied for one-dimensional geometry Permeation of solvent through the interface is taken into account It is shown that the rate determining process of motion of interface is the permeation of solvent through the bulk domains Generalization to three-dimensional case is also discussed.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2012
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.3698168